Weighing Water Quality
Water quality requirements can be dictated by the unit operation it serves, such as boiler feedwater, or can be impacted by the process from where the water is coming from, such as a tailings pond. Quality also can be determined by what water source is available, whether from a river or well water supply.
Understanding a water system for mining requires knowing the quality of the water throughout the operation. Assessing the quality of water is necessary to determine if it will be suitable for the application or if the water will require additional treatment.
While understanding water quality usually begins with water analysis, not all water analyses are adequate or even accurate. For daily operational control, testing with basic equipment may be sufficient, but it is unlikely the test will be good enough for system design purposes or regulatory reporting.
Designing an optimal water management system or operations unit typically requires an extensive array of constituents to be evaluated, which is beyond the capability of most operational or field labs.
Analysis for regulatory permits usually requires a certified and independent lab with traceable standards and reported quality control.
Increasing Water Quality Confidence
For operators faced with water analysis that may be of unknown origins or questionable accuracy, a few tests exist that can be performed to help increase confidence in the analysis or identify inaccuracies.
Figure 1 is an example of a water quality review and compares the number of cations to anions on an equivalent basis that should balance. The data also correlates the projected quantity of dissolved solids to the amount measured.
An adjustment is made in the table comparison due to the laboratory method to determine total dissolved solids (TDS). The TDS is a gravimetric test that causes the decomposition of the bicarbonate that would not compare well to the summation of the individual ions where this decomposition does not occur.
A mine operator should not expect exact values (indicated in ratios of exactly 1.0) in both the ionic balance and the TDS comparison. Instead, it is generally accepted that if these ratios are within a range of 0.9 to 1.1, the confidence of the analysis is good. If ratios are significantly off, the analyses may either be inaccurate or missing a significant component.